By W.A. E. McBryde

ISBN-10: 0080223443

ISBN-13: 9780080223445

Show description

Read Online or Download A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes PDF

Best organic books

Download PDF by Salo Gronowitz: Chemistry of Heterocyclic Compounds: Thiophene and its

Content material: bankruptcy I training of Thiophenes by means of Ring? Closure Reactions and from different Ring structures (pages 1–214): Salo GronowitzChapter II Theoretical Calculations on Thiophenes (pages 215–260): Anita Henriksson? EnfloChapter III certainly Occuring Thiophenes (pages 261–324): F. Bohlmann and C. ZderoChapter IV Thiophenes taking place in Petroleum, Shale Oil, and Coals (pages 325–352): G.

Download e-book for iPad: Organic Photochromes by A.V. El'tsov

Just a small a part of the various photochemical reactions in natural compounds lead to reversible structural alterations. The latter are accom­ panied through a transformation in actual homes, particularly, of digital spectra. it really is tempting to attempt to take advantage of this photochromic impression in quite a few structures for controlling and regulating gentle fluxes and for info recording.

Download PDF by Douglass F. Taber: Intramolecular Diels-Alder and Alder Ene Reactions

The Diels-Alder response has lengthy been a strong device in natural synthesis. in recent times, the Alder ene response has additionally accomplished a few prominence. From the start, it was once obvious that the intramolecular versions of those reactions will be possible. Many such were stated, however the effects are commonly scattered within the chemical literature.

Daniel Lednicer's Antineoplastic Drugs: Organic Syntheses PDF

The previous decade has obvious an important bring up of analysis geared toward getting to know new medications for treating melanoma, and the expanding variety of new antineoplastic medications authorized through regulatory organisations displays this. earlier, information at the synthesis of those more moderen brokers were scattered in a number of journals and in US and ecu patents.

Extra info for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

Sample text

0» 4>- -P- -P{13 (13 JD {13 *^J hO vo M ro oo W K) 0 0 VO O O O -P» 0 > ^>J W O co Ln o o o o o W rt O PC Ln O ^8 -P^ LO hO ho O O Ln O Sg S g g g s:o S o Ln O Ln O rt O tu ^ W M O Ln Ln O O Ô»S o o o O W rt O PC Ln O 3^ ■ > ÜJ M O O Ln n nn n ·*! 4 Metal ion (Continued) Temp. 0 - - - 19 73Bb ! 5* M(OH)2L M 2 (0H) 2 L 2 Nitrate Ag(I) Hg(I) Ammonia Ni(II) Ethylenediamine log 3 log X Temp. 1 KC1 30 11 67L var. 3 Pi - 1 7 . 5 11 59G 23i - 1 0 . 1 (Continued) Auxiliary Ligand A Metal Complex log K log ß log X Medium Temp.

00 25 0 . 7 12 Dt 61H 5-Chlorophenanthroline Fe(II) ? 3 (Continued) Metal ion Temp °C Fe(II) Medium M ? 74 59B Estim Rej 72Bf 5-Nitrophenanthroline Fe(II) Fe(III) ? 8 12 52B ? 40 Method Reference 12 59B 5-Phenylphenanthroline Fe(II) ? 1 12 52B ? 7 11 56Y 19 74Hb - 4,4'-Diethoxy-2,2f-Bipyridyl Ni(II) ? dil EtOH, aq. l Acidity Constants of Phenanthrolines Mixed or Non-aqueous Solvents Substituent Unsubstituted pKi Temp. 80 Medium Method Reference 50% aq. EtOH 1 48A 50% aq. Dioxane 1 61J 10% aq. 54 25 75% aq.

41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. 2 (Continued) pKi Temp. 23 25 50% aq. 38 25 50% aq.

Download PDF sample

A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes by W.A. E. McBryde


by Ronald
4.2

Rated 4.57 of 5 – based on 19 votes